{"id":37,"date":"2020-04-17T20:50:53","date_gmt":"2020-04-18T00:50:53","guid":{"rendered":"http:\/\/sites.nd.edu\/jaffelab\/?page_id=37"},"modified":"2025-12-04T14:04:23","modified_gmt":"2025-12-04T19:04:23","slug":"publications","status":"publish","type":"page","link":"https:\/\/sites.nd.edu\/jaffelab\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n

*If you are unable to access articles at the journal links provided below, please request a PDF by email.<\/em><\/p>\n\n\n\n

Current Work<\/h2>\n\n\n\n
\n
\n
    \n
  1. Torres-Cadena, R.; Dayaratne, W. L. N.; Lee, M.; Jaffe, A.* Pressure-induced coupling of hydrated 4,4′-bipyridine. Phys. Chem. Chem. Phys<\/em>. 2025<\/strong>, 27<\/em>, 23545<\/a>.

    Research data<\/a> supporting this publication.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
    \n
    \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
    \n
    \n
      \n
    1. Robertson, G. M.; Jaffe, A.* Structural and electronic tuning of hybrid metal thiocyanate N<\/em>-oxides. Dalton Trans<\/em>. 2025<\/strong>, 54<\/em>, 14648<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
      \n
      \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
      \n
      \n
        \n
      1. Morales Campos, J.; Beck, W. D.; Prokop, B. S.; Jaffe, A.* Iron-directed thermolysis of pyridine N-oxide in layered metal cyanides. ACS Mater. Lett<\/em>. 2025<\/strong>, 7<\/em>, 3512<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
        \n
        \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
        \n
        \n
          \n
        1. Padilla II, A. E.; Jaffe, A.* Anion Exchange in Bismuth Oxyhalides for Electronic Property Control and Isolation of BiON3<\/sub>. Inorg. Chem. Front. 2025<\/strong>, 12<\/em>, 8470<\/a>. (Inorganic Chemistry Frontiers Emerging Investigator Series 2024\u20132025<\/a>)<\/li>\n<\/ol>\n<\/div>\n\n\n\n
          \n
          \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
          \n
          \n
            \n
          1. Torres-Cadena, R.\u2021<\/sup>; Dayaratne, W. L. N.\u2021<\/sup>; Chen, H.-T.; Kovrigin, E. L.; Tucker, M. G.; Haberl, B.; Jaffe, A.* Negative Compressibility Transitions in Hybrid Metal Oxides. J. Am. Chem. Soc<\/em>. 2025<\/strong>, 147<\/em>, 25931<\/a>. (\u2021<\/sup>contributed equally)

            Research data<\/a> supporting this publication.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
            \n
            \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
            \n
            \n
              \n
            1. Dayaratne, W. L. N.; Torres-Cadena, R.; Walte, A. F.; Wan, S.; Morales Campos, J.; Jaffe, A.* A Hybrid Bronze Age: Progress and Potential in Mixed-Valence Organic-Inorganic Metal Oxides. Inorg<\/em>. Chem<\/em>. 2025<\/strong>, 64<\/em>, 12881<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
              \n
              \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
              \n
              \n
                \n
              1. Walte, A. F.; Torres-Cadena, R.; Dayaratne, W. L. N.; Jaffe, A.* Mixed-Metal Alloying in Hybrid Bronzes. J. Am. Chem. Soc<\/em>. 2024<\/strong>, 146<\/em>, 23699<\/a>.

                Research data<\/a> supporting this publication.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                \n
                \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                \n
                \n
                  \n
                1. Wan, S.; Musielak, N.; Oliver, A. G.; Jaffe, A.* Controlling Electron Delocalization in Vanadium-Based Hybrid Bronzes through Molecular Templation. Angew. Chem., Int. Ed<\/em>. 2023<\/strong>, 62<\/em>, e202314523.<\/a><\/li>\n<\/ol>\n<\/div>\n\n\n\n
                  \n
                  \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                  \n
                  \n
                    \n
                  1. Dayaratne, W. L. N.\u2021<\/sup>; Torres-Cadena, R.\u2021<\/sup>; Schmitt, B. P.; Westrick, E. M.; Jaffe, A.* Hybrid bronzes: mixed-valence organic-inorganic metal oxides as a tunable material platform. Chem. Sci<\/em>. 2023<\/strong>, 14<\/em>, 10756.<\/a> (\u2021<\/sup>contributed equally)<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                    \n
                    \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                      \n
                    1. Hartley, N. A.; Pugh, S.; Xu, Z.; Leong, D. C. Y.; Jaffe, A.; Forse, A. C. Quinone-functionalised carbons as new materials for electrochemical carbon dioxide capture. J. Mater. Chem. A<\/em> 2023<\/strong>, 11<\/em>, 16221.<\/a><\/li>\n<\/ol>\n\n\n\n

                      Previous Work<\/h2>\n\n\n\n
                      \n
                      \n
                        \n
                      1. Wolf, N. R.; Jaffe, A.; Slavney, A. H.; Mao, W. L.; Leppert, L.; Karunadasa, H. I. Tuning Defects in a Halide Double Perovskite with Pressure. J. Am. Chem. Soc<\/em>. 2022<\/strong>, 144<\/em>, 20763.<\/a><\/li>\n<\/ol>\n<\/div>\n\n\n\n
                        \n
                        \n
                        \"\"<\/figure>\n<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                        \n
                        \n
                          \n
                        1. Jaramillo, D. E.; Jaffe, A.; Snyder, B. E. R.; Smith, A.; Taw, E.; Rohde, R. C.; Dods, M. N.; DeSnoo, W.; Meihaus, K. R.; Harris, T. D.; Neaton, J. B.; Long, J. R. Metal\u2013organic frameworks as O2-selective adsorbents for air separations. Chem. Sci<\/em>. 2022<\/strong>, 13<\/em>, 10216.<\/a><\/li>\n<\/ol>\n<\/div>\n\n\n\n
                          \n
                          \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                            \n
                          1. Jaffe, A.\u2021<\/sup>; Zamkov, M.\u2021<\/sup> Perovskites for Detection of Low- and High-Energy Radiation. ACS Energy Lett<\/em>. 2022<\/strong>, 7<\/em>, 366<\/a>.<\/li>\n<\/ol>\n\n\n\n
                            \n
                            \n
                              \n
                            1. Jaffe, A.; Ziebel, M. E.; Halat, D. M.; Biggins, N.; Murphy, R. A.; Chakarawet, K.; Reimer, J. A.; Long, J. R. Selective, High-Temperature O2<\/sub> Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal\u2013Organic Frameworks. J. Am. Chem. Soc.<\/em> 2020<\/strong>, 142<\/em>, 14627.<\/a> (JACS Spotlight<\/a>)<\/em><\/li>\n<\/ol>\n<\/div>\n\n\n\n
                              \n
                              \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                              \n
                              \n
                                \n
                              1. Lee, J.-H.; Jaffe, A.; Karunadasa, H. I.; Neaton, J. B. Origins of the Pressure-Induced Phase Transition and Metallization in the Halide Perovskite (CH3<\/sub>NH3<\/sub>)PbI3<\/sub>. ACS Energy Lett. <\/em>2020<\/strong>, 5<\/em>, 2174<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                \n
                                \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                \n
                                \n
                                  \n
                                1. Jaffe, A.; Long, J. R. Ordered absences out of the blue. Nature<\/em> 2020<\/strong>, 578<\/em>, 222<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                  \n
                                  \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                  \n
                                  \n
                                    \n
                                  1. Jaffe, A.; Mack, S. A.; Lin, Y.; Mao, W. L.; Neaton, J. B.; Karunadasa, H. I. High Compression-Induced Conductivity in a Layered Cu\u2013Br Hybrid Perovskite. Angew. Chem., Int. Ed<\/em>., 2020<\/strong>, 59<\/em>, 4017<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                    \n
                                    \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                      \n
                                    1. Smith, M. D.; Crace, E. J.; Jaffe, A.; Karunadasa, H. I. The Diversity of Layered Halide Perovskites. Annu. Rev. Mater. Res<\/em>. 2018<\/strong>, 48<\/em>, 111<\/a>.<\/li>\n<\/ol>\n\n\n\n
                                      \n
                                      \n
                                        \n
                                      1. Jaffe, A.; Lin, Y.; Karunadasa, H. I. Halide Perovskites under Pressure: Accessing New Properties through Lattice Compression. ACS Energy Lett<\/em>., 2017<\/strong>, 2<\/em>, 1549<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                        \n
                                        \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                        \n
                                        \n
                                          \n
                                        1. Smith, M. D.\u2021<\/sup>; Jaffe, A.\u2021<\/sup>; Dohner, E. R.; Karunadasa, H. I. Structural Origins of Broadband Emission from Layered Pb\u2013Br Hybrid Perovskites. Chem. Sci<\/em>. 2017<\/strong>, 8<\/em>, 4497<\/a>. (\u2021<\/sup>contributed equally)<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                          \n
                                          \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                          \n
                                          \n
                                            \n
                                          1. George, N. C.; Brgoch, J.; Pell, A. J.; Cozzan, C.; Jaffe, A.; Dantelle, G.; Llobet, A.; Pintacuda, G.; Seshadri, R.; Chmelka, B. F. Correlating Local Compositions and Structures with the Macroscopic Optical Properties of Ce3+<\/sup>-doped CaSc2<\/sub>O4<\/sub>, an Efficient Green-Emitting Phosphor. Chem. Mater.<\/em> 2017<\/strong>, 29<\/em>, 3538<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                            \n
                                            \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                            \n
                                            \n
                                              \n
                                            1. Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. Pressure-Induced Metallization of the Halide Perovskite (CH3<\/sub>NH3<\/sub>)PbI3<\/sub>. J. Am. Chem. Soc.<\/em> 2017<\/strong>, 139<\/em>, 4330<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                              \n
                                              \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                              \n
                                              \n
                                                \n
                                              1. Smith, I. C.; Smith, M. D.; Jaffe, A.; Lin, Y.; Karunadasa, H. I. Between the Sheets: Post-Synthetic Transformations in Hybrid Perovskites. Chem. Mater<\/em>. 2017<\/strong>, 29<\/em>, 1868<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                \n
                                                \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                \n
                                                \n
                                                  \n
                                                1. Slavney, A. H.; Smaha, R. W.; Smith, I. C.; Jaffe, A.; Umeyama, D.; Karunadasa, H. I. Chemical Approaches to Addressing the Instability and Toxicity of Lead\u2013Halide Perovskite Absorbers. Inorg. Chem<\/em>. 2017<\/strong>, 56<\/em>, 46<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                  \n
                                                  \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                  \n
                                                  \n
                                                    \n
                                                  1. Jaffe, A.; Lin, Y.; Beavers, C. M.; Voss, J.; Mao, W. L.; Karunadasa, H. I. High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties. ACS Cent. Sci<\/em>. 2016<\/strong>, 2<\/em>, 201<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                    \n
                                                    \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                    \n
                                                    \n
                                                      \n
                                                    1. Jaffe, A.\u2021<\/sup>; Saldivar-Valdes, A.\u2021<\/sup>; Karunadasa, H. I. Quinone-Functionalized Carbon Black Cathodes for Lithium Batteries with High Power Densities. Chem. Mater<\/em>. 2015<\/strong>, 27<\/em>, 3568<\/a>. (\u2021<\/sup>contributed equally)<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                      \n
                                                      \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                      \n
                                                      \n
                                                        \n
                                                      1. Jaffe, A.\u2021<\/sup>; Lin, Y.\u2021<\/sup>; Mao, W. L.; Karunadasa, H. I. Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu\u2013Cl Hybrid Perovskite. J. Am. Chem. Soc<\/em>. 2015<\/strong>, 137<\/em>, 1673<\/a>. (\u2021<\/sup>contributed equally)<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                        \n
                                                        \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                        \n
                                                        \n
                                                          \n
                                                        1. Dohner, E. R.; Jaffe, A.; Bradshaw, L. R.; Karunadasa, H. I. Intrinsic White-Light Emission from Layered Perovskites. J. Am. Chem. Soc<\/em>. 2014<\/strong>, 136<\/em>, 13154<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                          \n
                                                          \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n
                                                          \n
                                                          \n
                                                            \n
                                                          1. Jaffe, A.; Karunadasa, H. I. Lithium Cycling in a Self-Assembled Copper Chloride\u2013Polyether Hybrid Electrode. <\/em>Inorg. Chem<\/em>. 2014<\/strong>, 53<\/em>, 6494<\/a>.<\/li>\n<\/ol>\n<\/div>\n\n\n\n
                                                            \n
                                                            \"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n

                                                            Copyright permissions<\/em>:<\/p>\n\n\n\n

                                                              \n
                                                            1. <\/li>\n<\/ol>\n\n\n\n
                                                                \n
                                                              1. Reprinted with permission from Dayaratne, W. L. N.; Torres-Cadena, R.; Walte, A. F.; Wan, S.; Morales Campos, J.; Jaffe, A. Inorg. Chem. 2025. Copyright 2025 American Chemical Society.<\/li>\n\n\n\n
                                                              2. Reprinted with permission from Walte, A. F.; Torres-Cadena, R.; Dayaratne, W. L. N.; Jaffe, A. J. Am. Chem. Soc. 2024. Copyright 2024 American Chemical Society.<\/li>\n\n\n\n
                                                              3. Reprinted with permission from The German Chemical Society. Wan, S.; Musielak, N.; Oliver, A. G.; Jaffe, A. Angew. Chem., Int. Ed. 2023, e202314523. Copyright 2023 John Wiley & Sons, Inc.<\/li>\n\n\n\n
                                                              4. Reprinted with permission from The Royal Society of Chemistry. Dayaratne, W. L.; Torres-Cadena, R.; Schmitt, B. P.; Westrick, E. M.; Jaffe, A. Chem. Sci. 2023, 14, 10756. Copyright 2023 Royal Society of Chemistry.<\/li>\n\n\n\n
                                                              5. Reprinted with permission from The Royal Society of Chemistry. Hartley, N. A.; Pugh, S.; Xu, Z.; Leong, D. C. Y.; Jaffe, A.; Forse, A. C. J. Mater. Chem. A 2023, 11, 16221. Copyright 2023 Royal Society of Chemistry.<\/li>\n\n\n\n
                                                              6. Reprinted with permission from Wolf, N. R.; Jaffe, A.; Slavney, A. H.; Mao, W. L.; Leppert, L.; Karunadasa, H. I. J. Am. Chem. Soc. 2022, 144, 20763. Copyright 2022 American Chemical Society.<\/li>\n\n\n\n
                                                              7. Reprinted with permission from The Royal Society of Chemistry. Jaramillo, D. E.; Jaffe, A.; Snyder, B. E. R.; Smith, A.; Taw, E.; Rohde, R. C.; Dods, M. N.; DeSnoo, W.; Meihaus, K. R.; Harris, T. D.; Neaton, J. B.; Long, J. R. Chem. Sci. 2022. Copyright 2022 Royal Society of Chemistry.<\/li>\n\n\n\n
                                                              8. Reprinted with permission from Jaffe, A.; Ziebel, M. E.; Halat, D. M.; Biggins, N.; Murphy, R. A.; Chakarawet, K.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2020, 142, 14627. Copyright 2020 American Chemical Society.<\/li>\n\n\n\n
                                                              9. Reprinted with permission from Lee, J.-H.; Jaffe, A.; Lin, Y.; Karunadasa, H. I.; Neaton, J. B. ACS Energy Lett. 2020, 5, 2174-2181.. Copyright 2020 American Chemical Society.<\/li>\n\n\n\n
                                                              10. …<\/li>\n\n\n\n
                                                              11. Reprinted with permission from The German Chemical Society. Jaffe, A.; Mack, S. A.; Lin, Y.; Mao, W. L.; Neaton, J. B.; Karunadasa, H. I. Angew. Chem., Int. Ed. 2020, 59, 4017. Copyright 2020 John Wiley & Sons, Inc.<\/li>\n\n\n\n
                                                              12. …<\/li>\n\n\n\n
                                                              13. Reprinted with permission from Jaffe, A.; Lin, Y.; Karunadasa, H. I. ACS Energy Lett. 2017, 2, 1549. Copyright 2017 American Chemical Society.<\/li>\n\n\n\n
                                                              14. Reprinted with permission from The Royal Society of Chemistry. Smith, M. D.; Jaffe, A.; Dohner, E. R.; Lindenberg, A. M.; Karunadasa, H. I. Chem. Sci. 2017, 8, 4497. Copyright 2017 Royal Society of Chemistry.<\/li>\n\n\n\n
                                                              15. Reprinted with permission from George, N. C.; Brgoch, J.; Pell, A. J.; Cozzan, C.; Jaffe, A.; Dantelle, G.; Llobet, A.; Pintacuda, G.; Seshadri, R.; Chmelka, B. F. Chem. Mater. 2017, 29, 3538. Copyright 2017 American Chemical Society.<\/li>\n\n\n\n
                                                              16. Reprinted with permission from Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. J. Am. Chem. Soc. 2017, 139, 4330. Copyright 2017 American Chemical Society.<\/li>\n\n\n\n
                                                              17. Reprinted with permission from Smith, I. C.; Smith, M. D.; Jaffe, A.; Lin, Y.; Karunadasa, H. I. Chem. Mater. 2017, 29, 1868. Copyright 2017 American Chemical Society.<\/li>\n\n\n\n
                                                              18. Reprinted with permission from Slavney, A. H.; Smaha, R. W.; Smith, I. C.; Jaffe, A.; Umeyama, D.; Karunadasa, H. I. Inorg. Chem. 2017, 56, 46. Copyright 2017 American Chemical Society.<\/li>\n\n\n\n
                                                              19. Reprinted with permission from Jaffe, A.; Lin, Y.; Beavers, C. M.; Voss, J.; Mao, W. L.; Karunadasa, H. I. ACS Cent. Sci. 2016, 2, 201. Copyright 2016 American Chemical Society.<\/li>\n\n\n\n
                                                              20. Reprinted with permission from Jaffe, A.; Saldivar Valdes, A.; Karunadasa, H. I. Chem. Mater. 2015, 27, 3568. Copyright 2015 American Chemical Society.<\/li>\n\n\n\n
                                                              21. Reprinted with permission from Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. J. Am. Chem. Soc. 2015, 137, 1673. Copyright 2015 American Chemical Society.<\/li>\n\n\n\n
                                                              22. Reprinted with permission from Dohner, E. R.; Jaffe, A.; Bradshaw, L. R.; Karunadasa, H. I. J. Am. Chem. Soc. 2014, 136, 13154. Copyright 2014 American Chemical Society.<\/li>\n\n\n\n
                                                              23. Reprinted with permission from Jaffe, A.; Karunadasa, H. I. Inorg. Chem. 2014, 53, 6494. Copyright 2014 American Chemical Society.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

                                                                *If you are unable to access articles at the journal links provided below, please request a PDF by email. Current Work Previous Work Copyright permissions:<\/p>\n","protected":false},"author":3733,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-37","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/pages\/37","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/users\/3733"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/comments?post=37"}],"version-history":[{"count":54,"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/pages\/37\/revisions"}],"predecessor-version":[{"id":754,"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/pages\/37\/revisions\/754"}],"wp:attachment":[{"href":"https:\/\/sites.nd.edu\/jaffelab\/wp-json\/wp\/v2\/media?parent=37"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}