{"id":270,"date":"2020-05-04T12:51:14","date_gmt":"2020-05-04T16:51:14","guid":{"rendered":"http:\/\/sites.nd.edu\/nazli-turan\/?p=270"},"modified":"2021-01-15T14:27:06","modified_gmt":"2021-01-15T18:27:06","slug":"excited-electrons-driving-a-reaction-have-been-observed-for-the-first-time","status":"publish","type":"post","link":"https:\/\/sites.nd.edu\/nazli-turan\/2020\/05\/04\/excited-electrons-driving-a-reaction-have-been-observed-for-the-first-time\/","title":{"rendered":"Excited electrons driving a reaction have been observed for the first time"},"content":{"rendered":"<blockquote><p>&#8220;In past molecular movies, we have been able to see how atomic nuclei move during a chemical reaction,&#8221; said Peter Weber, a chemistry professor at Brown and senior author of the report. &#8220;But the chemical bonding itself, which is a result of the redistribution of electrons, was invisible. Now the door is open to watching the chemical bonds change during reactions.&#8221;<\/p><\/blockquote>\n<p><!--more--><\/p>\n<p>This spectacular article has been published in <a href=\"https:\/\/www.nature.com\/articles\/s41467-020-15680-4\">Nature Communications<\/a> recently. The electrons were excited with light adjusted by a laser. They stayed in the excited state about 200 femtoseconds and that was enough to capture the redistribution of electrons by researchers.<\/p>\n<figure id=\"attachment_271\" aria-describedby=\"caption-attachment-271\" style=\"width: 2400px\" class=\"wp-caption alignright\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-271 size-full\" src=\"http:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl.jpg\" alt=\"\" width=\"2400\" height=\"1200\" srcset=\"https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl.jpg 2400w, https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl-300x150.jpg 300w, https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl-1024x512.jpg 1024w, https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl-768x384.jpg 768w, https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl-1536x768.jpg 1536w, https:\/\/sites.nd.edu\/nazli-turan\/files\/2020\/05\/electfirstdirectl-2048x1024.jpg 2048w\" sizes=\"auto, (max-width: 2400px) 100vw, 2400px\" \/><figcaption id=\"caption-attachment-271\" class=\"wp-caption-text\">Scientists have directly seen the first step in a light-driven chemical reaction for the first time. They used an X-ray free-electron laser at SLAC to capture nearly instantaneous changes in the distribution of electrons when light hit a ring-shaped molecule called CHD. Within 30 femtoseconds, or millionths of a billionth of a second, clouds of electrons deformed into larger, more diffuse clouds corresponding to an excited electronic state. Credit: Thomas Splettstoesser\/SCIstyle, Terry Anderson\/SLAC National Accelerator Laboratory<\/figcaption><\/figure>\n<p>The more detailed explanations can be found here: <a href=\"https:\/\/phys.org\/news\/2020-05-electrons-chemical-reaction.html?fbclid=IwAR3FQBEPBqpTr4hubBiKGxvdnfLrKEczErX8_sxBEh5AhPrctpf9v1d0jEM\">First direct look at how light excites electrons to kick off a chemical reaction<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>&#8220;In past molecular movies, we have been able to see how atomic nuclei move during a chemical reaction,&#8221; said Peter Weber, a chemistry professor at Brown and senior author of the report. &#8220;But the chemical bonding itself, which is a result of the redistribution of electrons, was invisible. Now the door is open to watching [&hellip;]<\/p>\n","protected":false},"author":3115,"featured_media":273,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[302453],"tags":[5070],"class_list":["post-270","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-science-news","tag-chemistry"],"_links":{"self":[{"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/posts\/270","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/users\/3115"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/comments?post=270"}],"version-history":[{"count":3,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/posts\/270\/revisions"}],"predecessor-version":[{"id":413,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/posts\/270\/revisions\/413"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/media\/273"}],"wp:attachment":[{"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/media?parent=270"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/categories?post=270"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/sites.nd.edu\/nazli-turan\/wp-json\/wp\/v2\/tags?post=270"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}