Publications

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Current Work

  1. Walte, A. F.; Torres-Cadena, R.; Dayaratne, W. L. N.; Jaffe, A.* Mixed-Metal Alloying in Hybrid Bronzes. J. Am. Chem. Soc. 2024, 146, 23699.
  1. Wan, S.; Musielak, N.; Oliver, A. G.; Jaffe, A.* Controlling Electron Delocalization in Vanadium-Based Hybrid Bronzes through Molecular Templation. Angew. Chem., Int. Ed. 2023, 62, e202314523.
  1. Dayaratne, W. L. N.‡; Torres-Cadena, R.‡; Schmitt, B. P.; Westrick, E. M.; Jaffe, A.* Hybrid bronzes: mixed-valence organic-inorganic metal oxides as a tunable material platform. Chem. Sci. 2023, 14, 10756. (‡contributed equally)
  1. Hartley, N. A.; Pugh, S.; Xu, Z.; Leong, D. C. Y.; Jaffe, A.; Forse, A. C. Quinone-functionalised carbons as new materials for electrochemical carbon dioxide capture. J. Mater. Chem. A 2023, 11, 16221.

Previous Work

  1. Wolf, N. R.; Jaffe, A.; Slavney, A. H.; Mao, W. L.; Leppert, L.; Karunadasa, H. I. Tuning Defects in a Halide Double Perovskite with Pressure. J. Am. Chem. Soc. 2022, 144, 20763.
  1. Jaramillo, D. E.; Jaffe, A.; Snyder, B. E. R.; Smith, A.; Taw, E.; Rohde, R. C.; Dods, M. N.; DeSnoo, W.; Meihaus, K. R.; Harris, T. D.; Neaton, J. B.; Long, J. R. Metal–organic frameworks as O2-selective adsorbents for air separations. Chem. Sci. 2022, 13, 10216.
  1. Jaffe, A.; Ziebel, M. E.; Halat, D. M.; Biggins, N.; Murphy, R. A.; Chakarawet, K.; Reimer, J. A.; Long, J. R. Selective, High-Temperature O2 Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal–Organic Frameworks. J. Am. Chem. Soc. 2020, 142, 14627. (JACS Spotlight)
  1. Lee, J.-H.; Jaffe, A.; Karunadasa, H. I.; Neaton, J. B. Origins of the Pressure-Induced Phase Transition and Metallization in the Halide Perovskite (CH3NH3)PbI3. ACS Energy Lett. 2020, 5, 2174.
  1. Jaffe, A.; Long, J. R. Ordered absences out of the blue. Nature 2020, 578, 222.
  1. Jaffe, A.; Mack, S. A.; Lin, Y.; Mao, W. L.; Neaton, J. B.; Karunadasa, H. I. High Compression-Induced Conductivity in a Layered Cu–Br Hybrid Perovskite. Angew. Chem., Int. Ed., 2020, 59, 4017.
  1. Smith, M. D.; Crace, E. J.; Jaffe, A.; Karunadasa, H. I. The Diversity of Layered Halide Perovskites. Annu. Rev. Mater. Res. 2018, 48, 111.
  1. Jaffe, A.; Lin, Y.; Karunadasa, H. I. Halide Perovskites under Pressure: Accessing New Properties through Lattice Compression. ACS Energy Lett., 2017, 2, 1549.
  1. Smith, M. D.‡; Jaffe, A.‡; Dohner, E. R.; Karunadasa, H. I. Structural Origins of Broadband Emission from Layered Pb–Br Hybrid Perovskites. Chem. Sci. 2017, 8, 4497. (‡contributed equally)
  1. George, N. C.; Brgoch, J.; Pell, A. J.; Cozzan, C.; Jaffe, A.; Dantelle, G.; Llobet, A.; Pintacuda, G.; Seshadri, R.; Chmelka, B. F. Correlating Local Compositions and Structures with the Macroscopic Optical Properties of Ce3+-doped CaSc2O4, an Efficient Green-Emitting Phosphor. Chem. Mater. 2017, 29, 3538.
  1. Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. Pressure-Induced Metallization of the Halide Perovskite (CH3NH3)PbI3. J. Am. Chem. Soc. 2017, 139, 4330.
  1. Smith, I. C.; Smith, M. D.; Jaffe, A.; Lin, Y.; Karunadasa, H. I. Between the Sheets: Post-Synthetic Transformations in Hybrid Perovskites. Chem. Mater. 2017, 29, 1868.
  1. Slavney, A. H.; Smaha, R. W.; Smith, I. C.; Jaffe, A.; Umeyama, D.; Karunadasa, H. I. Chemical Approaches to Addressing the Instability and Toxicity of Lead–Halide Perovskite Absorbers. Inorg. Chem. 2017, 56, 46.
  1. Jaffe, A.; Lin, Y.; Beavers, C. M.; Voss, J.; Mao, W. L.; Karunadasa, H. I. High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties. ACS Cent. Sci. 2016, 2, 201.
  1. Jaffe, A.‡; Saldivar-Valdes, A.‡; Karunadasa, H. I. Quinone-Functionalized Carbon Black Cathodes for Lithium Batteries with High Power Densities. Chem. Mater. 2015, 27, 3568. (‡contributed equally)
  1. Jaffe, A.‡; Lin, Y.‡; Mao, W. L.; Karunadasa, H. I. Pressure-Induced Conductivity and Yellow-to-Black Piezochromism in a Layered Cu–Cl Hybrid Perovskite. J. Am. Chem. Soc. 2015, 137, 1673. (‡contributed equally)
  1. Dohner, E. R.; Jaffe, A.; Bradshaw, L. R.; Karunadasa, H. I. Intrinsic White-Light Emission from Layered Perovskites. J. Am. Chem. Soc. 2014, 136, 13154.
  1. Jaffe, A.; Karunadasa, H. I. Lithium Cycling in a Self-Assembled Copper Chloride–Polyether Hybrid Electrode. Inorg. Chem. 2014, 53, 6494.

Copyright permissions:

  1. Reprinted with permission from Walte, A. F.; Torres-Cadena, R.; Dayaratne, W. L. N.; Jaffe, A. J. Am. Chem. Soc. 2024. Copyright 2024 American Chemical Society.
  2. Reprinted with permission from The German Chemical Society. Wan, S.; Musielak, N.; Oliver, A. G.; Jaffe, A. Angew. Chem., Int. Ed. 2023, e202314523. Copyright 2023 John Wiley & Sons, Inc.
  3. Reprinted with permission from The Royal Society of Chemistry. Dayaratne, W. L.; Torres-Cadena, R.; Schmitt, B. P.; Westrick, E. M.; Jaffe, A. Chem. Sci. 2023, 14, 10756. Copyright 2023 Royal Society of Chemistry.
  4. Reprinted with permission from The Royal Society of Chemistry. Hartley, N. A.; Pugh, S.; Xu, Z.; Leong, D. C. Y.; Jaffe, A.; Forse, A. C. J. Mater. Chem. A 2023, 11, 16221. Copyright 2023 Royal Society of Chemistry.
  5. Reprinted with permission from Wolf, N. R.; Jaffe, A.; Slavney, A. H.; Mao, W. L.; Leppert, L.; Karunadasa, H. I. J. Am. Chem. Soc. 2022, 144, 20763. Copyright 2022 American Chemical Society.
  6. Reprinted with permission from The Royal Society of Chemistry. Jaramillo, D. E.; Jaffe, A.; Snyder, B. E. R.; Smith, A.; Taw, E.; Rohde, R. C.; Dods, M. N.; DeSnoo, W.; Meihaus, K. R.; Harris, T. D.; Neaton, J. B.; Long, J. R. Chem. Sci. 2022. Copyright 2022 Royal Society of Chemistry.
  7. Reprinted with permission from Jaffe, A.; Ziebel, M. E.; Halat, D. M.; Biggins, N.; Murphy, R. A.; Chakarawet, K.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2020, 142, 14627. Copyright 2020 American Chemical Society.
  8. Reprinted with permission from Lee, J.-H.; Jaffe, A.; Lin, Y.; Karunadasa, H. I.; Neaton, J. B. ACS Energy Lett. 2020, 5, 2174-2181.. Copyright 2020 American Chemical Society.
  9. …
  10. Reprinted with permission from The German Chemical Society. Jaffe, A.; Mack, S. A.; Lin, Y.; Mao, W. L.; Neaton, J. B.; Karunadasa, H. I. Angew. Chem., Int. Ed. 2020, 59, 4017. Copyright 2020 John Wiley & Sons, Inc.
  11. …
  12. Reprinted with permission from Jaffe, A.; Lin, Y.; Karunadasa, H. I. ACS Energy Lett. 2017, 2, 1549. Copyright 2017 American Chemical Society.
  13. Reprinted with permission from The Royal Society of Chemistry. Smith, M. D.; Jaffe, A.; Dohner, E. R.; Lindenberg, A. M.; Karunadasa, H. I. Chem. Sci. 2017, 8, 4497. Copyright 2017 Royal Society of Chemistry.
  14. Reprinted with permission from George, N. C.; Brgoch, J.; Pell, A. J.; Cozzan, C.; Jaffe, A.; Dantelle, G.; Llobet, A.; Pintacuda, G.; Seshadri, R.; Chmelka, B. F. Chem. Mater. 2017, 29, 3538. Copyright 2017 American Chemical Society.
  15. Reprinted with permission from Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. J. Am. Chem. Soc. 2017, 139, 4330. Copyright 2017 American Chemical Society.
  16. Reprinted with permission from Smith, I. C.; Smith, M. D.; Jaffe, A.; Lin, Y.; Karunadasa, H. I. Chem. Mater. 2017, 29, 1868. Copyright 2017 American Chemical Society.
  17. Reprinted with permission from Slavney, A. H.; Smaha, R. W.; Smith, I. C.; Jaffe, A.; Umeyama, D.; Karunadasa, H. I. Inorg. Chem. 2017, 56, 46. Copyright 2017 American Chemical Society.
  18. Reprinted with permission from Jaffe, A.; Lin, Y.; Beavers, C. M.; Voss, J.; Mao, W. L.; Karunadasa, H. I. ACS Cent. Sci. 2016, 2, 201. Copyright 2016 American Chemical Society.
  19. Reprinted with permission from Jaffe, A.; Saldivar Valdes, A.; Karunadasa, H. I. Chem. Mater. 2015, 27, 3568. Copyright 2015 American Chemical Society.
  20. Reprinted with permission from Jaffe, A.; Lin, Y.; Mao, W. L.; Karunadasa, H. I. J. Am. Chem. Soc. 2015, 137, 1673. Copyright 2015 American Chemical Society.
  21. Reprinted with permission from Dohner, E. R.; Jaffe, A.; Bradshaw, L. R.; Karunadasa, H. I. J. Am. Chem. Soc. 2014, 136, 13154. Copyright 2014 American Chemical Society.
  22. Reprinted with permission from Jaffe, A.; Karunadasa, H. I. Inorg. Chem. 2014, 53, 6494. Copyright 2014 American Chemical Society.